…is a mixed bag.
By printing “black” I mean printing using only black ink or toner, also known as grayscale. This works on Windows (10) but not macOS. Unsure about GNU/Linux OSes, but according to this page—
Also from that page is a hint to enable it. If you open about:config (from the location bar of Firefox) and search for “monochrome” you can find (or create if need be) a setting titled print.cups.monochrome.extra_settings
and enter the appropriate variable and value for your printer. Which may require some sleuthing inside the PPD for your printer as not all companies use the same pair. In my case, printing to the parasite (an EFI/Fiery controller) on my Konica/Minolta “digital press” requires a value of EFColorMode:Grayscale
in the above mentioned setting.